<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-00940154</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-24T03:55:44+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Developpement of a simple method for rapid determination of As(III) and total As in drinking water</title>
            <author role="aut">
              <persName>
                <forename type="first">Jérôme</forename>
                <surname>Michon</surname>
              </persName>
              <idno type="halauthorid">527017-0</idno>
              <affiliation ref="#struct-74243"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Raad</forename>
                <surname>Al Shukry</surname>
              </persName>
              <idno type="halauthorid">793473-0</idno>
              <affiliation ref="#struct-74243"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Christophe</forename>
                <surname>Dagot</surname>
              </persName>
              <email type="md5">048c7f4b39c6b8e263c8bf0637e14d08</email>
              <email type="domain">unilim.fr</email>
              <idno type="idhal" notation="numeric">786361</idno>
              <idno type="halauthorid" notation="string">602456-786361</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-3632-0420</idno>
              <idno type="IDREF">https://www.idref.fr/033641781</idno>
              <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=24kIQ68AAAAJ</idno>
              <idno type="VIAF">https://viaf.org/viaf/29627845</idno>
              <idno type="ISNI">http://isni.org/isni/0000000121260459</idno>
              <affiliation ref="#struct-74243"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Véronique</forename>
                <surname>Deluchat</surname>
              </persName>
              <email type="md5">daaff47f786c500c72bb4510d4aa0184</email>
              <email type="domain">unilim.fr</email>
              <idno type="idhal" notation="string">veronique-deluchat</idno>
              <idno type="idhal" notation="numeric">1350403</idno>
              <idno type="halauthorid" notation="string">500444-1350403</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-9433-5658</idno>
              <idno type="IDREF">https://www.idref.fr/119984504</idno>
              <idno type="ISNI">http://isni.org/isni/0000000359219747</idno>
              <idno type="VIAF">https://viaf.org/viaf/215097267</idno>
              <affiliation ref="#struct-74243"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Véronique</forename>
                <surname>Deluchat</surname>
              </persName>
              <email type="md5">daaff47f786c500c72bb4510d4aa0184</email>
              <email type="domain">unilim.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2014-01-31 15:09:15</date>
              <date type="whenModified">2025-02-10 13:45:58</date>
              <date type="whenReleased">2014-01-31 15:09:15</date>
              <date type="whenProduced">2005</date>
              <ref type="externalLink" target="https://api.istex.fr/ark:/67375/80W-NLDPT4VL-M/fulltext.pdf?sid=hal"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="188791">
                <persName>
                  <forename>Véronique</forename>
                  <surname>Deluchat</surname>
                </persName>
                <email type="md5">daaff47f786c500c72bb4510d4aa0184</email>
                <email type="domain">unilim.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-00940154</idno>
            <idno type="halUri">https://unilim.hal.science/hal-00940154</idno>
            <idno type="halBibtex">michon:hal-00940154</idno>
            <idno type="halRefHtml">&lt;i&gt;European journal of water quality - Journal européen d'hydrologie&lt;/i&gt;, 2005, 36, pp.167-178. &lt;a target="_blank" href="https://dx.doi.org/10.1051/water/20053602167"&gt;&amp;#x27E8;10.1051/water/20053602167&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">European journal of water quality - Journal européen d'hydrologie, 2005, 36, pp.167-178. &amp;#x27E8;10.1051/water/20053602167&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="SDE">Sciences De l'Environnement</idno>
            <idno type="stamp" n="UNILIM">Université de Limoges</idno>
            <idno type="stamp" n="GRESE" corresp="UNILIM">Groupement de Recherche Eau, Sol, Environnement</idno>
            <idno type="stamp" n="GIP-BE">GIP Bretagne Environnement</idno>
            <idno type="stamp" n="GEIST" corresp="UNILIM">Génomique, environnement, immunité, thérapeutique</idno>
            <idno type="stamp" n="PEIRENE" corresp="UNILIM">PEIRENE</idno>
            <idno type="stamp" n="OMEGAHEALTH" corresp="UNILIM">OmegaHealth</idno>
            <idno type="stamp" n="LABCIS" corresp="UNILIM">Laboratoire des Agroressources, Biomolécules et Chimie pour l’Innovation en Santé</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Developpement of a simple method for rapid determination of As(III) and total As in drinking water</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Jérôme</forename>
                    <surname>Michon</surname>
                  </persName>
                  <idno type="halauthorid">527017-0</idno>
                  <affiliation ref="#struct-74243"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Raad</forename>
                    <surname>Al Shukry</surname>
                  </persName>
                  <idno type="halauthorid">793473-0</idno>
                  <affiliation ref="#struct-74243"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Christophe</forename>
                    <surname>Dagot</surname>
                  </persName>
                  <email type="md5">048c7f4b39c6b8e263c8bf0637e14d08</email>
                  <email type="domain">unilim.fr</email>
                  <idno type="idhal" notation="numeric">786361</idno>
                  <idno type="halauthorid" notation="string">602456-786361</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-3632-0420</idno>
                  <idno type="IDREF">https://www.idref.fr/033641781</idno>
                  <idno type="GOOGLE SCHOLAR">https://scholar.google.fr/citations?user=24kIQ68AAAAJ</idno>
                  <idno type="VIAF">https://viaf.org/viaf/29627845</idno>
                  <idno type="ISNI">http://isni.org/isni/0000000121260459</idno>
                  <affiliation ref="#struct-74243"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Véronique</forename>
                    <surname>Deluchat</surname>
                  </persName>
                  <email type="md5">daaff47f786c500c72bb4510d4aa0184</email>
                  <email type="domain">unilim.fr</email>
                  <idno type="idhal" notation="string">veronique-deluchat</idno>
                  <idno type="idhal" notation="numeric">1350403</idno>
                  <idno type="halauthorid" notation="string">500444-1350403</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-9433-5658</idno>
                  <idno type="IDREF">https://www.idref.fr/119984504</idno>
                  <idno type="ISNI">http://isni.org/isni/0000000359219747</idno>
                  <idno type="VIAF">https://viaf.org/viaf/215097267</idno>
                  <affiliation ref="#struct-74243"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="OLD">78165</idno>
                <idno type="issn">1818-8710</idno>
                <idno type="eissn">2100-0646</idno>
                <title level="j">European journal of water quality - Journal européen d'hydrologie</title>
                <imprint>
                  <publisher>EDP sciences</publisher>
                  <biblScope unit="volume">36</biblScope>
                  <biblScope unit="pp">167-178</biblScope>
                  <date type="datePub">2005</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1051/water/20053602167</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">arsenic determination</term>
                <term xml:lang="en">HG-AAS</term>
                <term xml:lang="en">drinking water</term>
                <term xml:lang="en">artificial water</term>
              </keywords>
              <classCode scheme="halDomain" n="sde.ie">Environmental Sciences/Environmental Engineering</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Inorganic arsenic, a term which encompasses both As(III) and As(V) species, constitutes the highest toxicological risk associated with arsenic in water opposite to organic arsenic species. Besides, Arsenic standard in drinking water has been lowered from 50 to 10 µg.L-1. Nevertheless, the degrees of toxicity for As(III) and As(V) are so different that it is not sufficient to determine the total content of arsenic in a given sample in order to estimate its physiological or environmental risks. Therefore, speciation of arsenic in water sample shows an increasing interest. In this work, a simple and rapid procedure was developed for the direct determination of As(III) in drinking water by Hydride Generation Atomic Absorption Spectrometry (HG-AAS) without pre-reduction of As(V). The principle of this method is to volatilise arsenic from As(III) to arsine AsH3(g) according to an apparatus equipped with a gas-liquid separator and a quartz cell. Nevertheless, if determination of total arsenic by HG-AAS technique using sodium borohydride (NaBH4) and hydrochloric acid (HCl) is well known, the application of the method for As(III) estimation is more difficult. Indeed, it is important to define a pH range in the tri-junction point of sample borohydride-acid. So, in order to overcome this problem, citric acid has been used for selective hydride formation of As(III). The following parameters were evaluated: first, the needed quantity of citric acid and NaBH4 to achieve complete reduction of As(III) without reduction of As(V); next, the carrier flow rate and the time necessary to perform the best arsine formation. Finally, measurements were performed in de-ionised water and artificial water but also in natural water. The optimised protocol for As(III) determination in drinking water was the next one: the sample was mixed with 0.2 M citric acid and 0.1% (w/v) NaBH4, this last one prepared in a 0.2% (w/v) NaOH solution. The flow rates were of 6.5, 1.0 and 1.0 mL.min-1for sample, NaBH4 and citric acid respectively. The optimised pH range obtained in the tri-junction point was of 2.5 - 3.5. This method was shown to be satisfactory for determination of traces arsenic in water samples. Thus, a calibration range was obtained for As(III) concentration between 0.5 and 20 µg.L-1 with a detection limit of 0.1 µg.L-1 and a quantification limit of 0.3 µg.L-1. A relative standard deviation value, based on three replicate measurements, below 3% was attained. Recovery studies of different added concentrations of As(III) in artificial and natural water samples were between 96 and 105%. The essay of a certified reference material solution was 5.2 ± 0.3 µg.L-1 (certified value 5.0 ± 0.1 µg.L-1).</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-74243" status="OLD">
          <idno type="IdRef">144802015</idno>
          <idno type="RNSR">200815559G</idno>
          <orgName>Groupement de Recherche Eau, Sol, Environnement</orgName>
          <orgName type="acronym">GRESE</orgName>
          <date type="start">2008-01-01</date>
          <date type="end">2017-12-31</date>
          <desc>
            <address>
              <addrLine>Faculté des sciences et techniques 123 Avenue Albert THOMAS 87060 LIMOGES</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.unilim.fr/filiere-eau/</ref>
          </desc>
          <listRelation>
            <relation name="EA4330" active="#struct-5928" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-5928" status="VALID">
          <idno type="IdRef">026403315</idno>
          <idno type="ISNI">0000000121654861</idno>
          <idno type="ROR">https://ror.org/02cp04407</idno>
          <orgName>Université de Limoges</orgName>
          <orgName type="acronym">UNILIM</orgName>
          <date type="start">1968-10-01</date>
          <desc>
            <address>
              <addrLine>33 rue François Mitterrand BP23204 87032 Limoges</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.unilim.fr</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>