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Article Dans Une Revue Molecules Année : 2020

In Depth Analysis of Photovoltaic Performance of Chlorophyll Derivative-Based “All Solid-State” Dye-Sensitized Solar Cells

Clémence Rose
  • Fonction : Auteur
David Beljonne

Résumé

Chlorophyll a derivatives were integrated in "all solid-state" dye sensitized solar cells (DSSCs) with a mesoporous TiO 2 electrode and 2 ,2 ,7,7-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9-spirobifluorene as the hole-transport material. Despite modest power conversion efficiencies (PCEs) between 0.26% and 0.55% achieved for these chlorin dyes, a systematic investigation was carried out in order to elucidate their main limitations. To provide a comprehensive understanding of the parameters (structure, nature of the anchoring group, adsorption. . .) and their relationship with the PCEs, density functional theory (DFT) calculations, optical and photovoltaic studies and electron paramagnetic resonance analysis exploiting the 4-carboxy-TEMPO spin probe were combined. The recombination kinetics, the frontier molecular orbitals of these DSSCs and the adsorption efficiency onto the TiO 2 surface were found to be the key parameters that govern their photovoltaic response.
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hal-02427794 , version 1 (06-07-2020)

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Michèle Chevrier, Alberto Fattori, Laurent Lasser, Clément Kotras, Clémence Rose, et al.. In Depth Analysis of Photovoltaic Performance of Chlorophyll Derivative-Based “All Solid-State” Dye-Sensitized Solar Cells. Molecules, 2020, 25 (1), pp.198. ⟨10.3390/molecules25010198⟩. ⟨hal-02427794⟩
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